GRACO INC. -- 206-994,THROAT SEAL LIQUID (TSL) -- 9150-01-047-9667
===================== Product Identification ===================== Product ID:206-994,THROAT SEAL LIQUID (TSL) MSDS Date:11/01/2000 FSC:9150 NIIN:01-047-9667 === Responsible Party === Company Name:GRACO INC. Address:4050 OLSON MEMORIAL HWY Box:1441 City:MINNEAPOLIS State:MN ZIP:55440-1441 Country:US Info Phone Num:612-623-6646 Emergency Phone Num:612-623-6646 Resp. Party Other MSDS Num.:307765 Preparer's Name:NOT PROVIDED Chemtrec Ind/Phone:(800)424-9300 CAGE:25980 === Contractor Identification === Company Name:AMERICAN INK AND OIL CORP Address:33 ENDICOTT STREET Box:City:NORWOOD State:MA ZIP:02062-3006 Country:US Phone:781-762-0026 / FAX: 781-762-1617 Contract Num:SP0450-01-M-LD17 CAGE:82956 Company Name:GRACO INC. Address:4050 OLSON MEMORIAL HWY Box:1441 City:MINNEAPOLIS State:MN ZIP:55440-1441 Country:US Phone:612-623-6646 CAGE:25980 ============= Composition/Information on Ingredients ============= Ingred Name:TRICRESYL PHOSPHATE CAS:1330-78-5 RTECS #:TD0175000 = Wt:100. Other REC Limits:NOT PROVIDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) > 5,000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS: EYES: MINIMALLY IRRITATING TO THE EYES IF MISTED. SKIN: NO SIGNIFICANT HEALTH HAZARDS IDENTIFIED. INHALATION: MAY BE IRRITATING TO THE RESPIRATORY SYSTEM IF MISTED. INGESTION : SWALLOWING LARGE QUANTITIES MAY CAUSE NEUROLOGICAL DISTURBANCES WHICH MAY PROGRESS TO DELAYED NEUROTOXICITY CHARACTERIZED BY ATAXIA AND TREMORS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: MINIMALLY IRRITATING TO THE EYES IF MISTED. INHALATION: MAY BE IRRITATING TO THE RESPIRATORY SYSTEM IF MISTED. INGESTION: SWALLOWING LARGE QUANTITIES MAY CAUSE NEUROLOGICAL DISTURBANCES WHICH MA Y PROGRESS TO DELAYED NEUROTOXICITY CHARACTERIZED BY ATAXIA AND TREMORS. Medical Cond Aggravated by Exposure:NOT PROVIDED ======================= First Aid Measures ======================= First Aid:EYE: WASH EYES WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: WASH EXPOSED SKIN WITH SOAP AND WATER. INHALATION: EFFECTS FROM INHALATION ARE NOT EXPECTED, HOWEVER IF THEY OCCUR, MOVE THE VICTIM TO FRESH AIR AND GET MEDICAL ATTENTION AS NECESSARY. INGESTIN: CONTACT THE LOCAL POISON CONTROL CENTER OR A PHYSICIAN FOR INSTRUCTIONS. DO NOT INDU CE VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS INDIVIDUAL. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=225.C, 437.F Autoignition Temp:=607.2C, 1125.F Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, MULTIPURPOSE FOAM. Fire Fighting Procedures:IN FIRES INVOLVING THIS MATERIAL, WEAR FULL PROTECTIVE CLOTHING, INCLUDING SELF CONTAINED BREATHING APPARATUS (SCBA). Unusual Fire/Explosion Hazard:SLIGHTLY COMBUSTIBLE; NO EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:LESS THAN 1 GALLON: ABSORB SPILLED MATERIAL WITH COMMERCIAL OIL ABSORBENT MATERIAL. SHOVEL ABSORBED SPILL INTO CONTAINERS FOR DISPOSAL. MORE THAN 1 GALLON: KEEP MATERIAL OUT OF STREAMS AND SEWERS. ABS ORB SPILLED MATERIAL ON COMMERCIAL OIL ABSORBENT OR SAND. USE ABSORBENT TO "DIKE" SPILL AREA IF NECESSARY TO PREVENT SPREAD. SHOVEL ABSORBED MATERIAL INTO A DOT APPROVED CONTAINER AND DISPOSE. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:HANDLING: AVOID GENERATION OF MISTS IN OCCUPIED AREAS. STORAGE: STORE IN CLOSED CONTAINERS WHEN NOT IN USE. Other Precautions:NOT PROVIDED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN HIGH TEMPERATURE APPLICATIONS OR WHERE EXPOSURE TO MISTING IS EXPECTED, USE NIOSH APPROVED ORGANIC VAPOR RESPIRATORY WITH MIST PREFILTER. USE SELF CONTAINED BREATHING APPARATUS IN EMERGENCY SITUATI ONS. Ventilation:DILUTION (GENERAL) VENTILATION IS NORMALLY SUFFICIENT IF HANDLED AT ROOM TEMP. AT HIGH TEMP OR MISTING IS ANTICIPATED, LOCAL EXHAUST VENTILATION IS RECOMMENDED. Protective Gloves:NOT PROVIDED Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:APRON, IMPERVIOUS CLOTHING, AND RUBBER BOOTS IF SPLASHING IS EXPECTED. Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V6 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:241 TO 255 DEG C @ 4 M Melt/Freeze Pt:<-40.C, -40.F Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:0.033 @ 150 DEG C (284 F) Vapor Density:N/E Spec Gravity:1.160 TO 1.175 @ 20 DEG C Viscosity:NOT PROVIDED Evaporation Rate & Reference:NOT PROVIDED Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR LIQUID, ODORLESS. Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE IDENTIFIED Hazardous Decomposition Products:UNDER FIRE CONDITIONS, PHOSPHOROUS OXIDES MAY FORM. NO DECOMPOSITION IN NORMAL USE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:EYE IRRITATION: MINIMALLY IRRITATING (RABBIT) (FMC 191-1209); SKIN IRRITATION: NON-IRRITATING (RABBIT) (FMC 191-1210); SKIN ABSORPTION: LD50 >10,000 MG/KG (RABBIT) (FMC ICD.T76-030); INHALATION - LC50 >4.25 MG/LITER (RAT) (MAXIMUM ATTAINABLE CONCENTRATION) (FMC 191-1211); ORAL-LD50 >5000 MG/KG (RAT) (FMC 191-1211). ===================== Ecological Information ===================== Ecological:96 HR LC50 (RAINBOW TROUT) = 0.75 (0.54-1.04) MG/L; 96 HR LC50 (FATHEAD MINNOW) = 100 MG/L; 48 HR LC50 (DAPHNIA MAGNA) = 0.27 (0.21-0.33) MG/L; 96 HR LC50 (BLUEGILL SUNFISH)=7000 MG/L. BIODEGRADATION IS EXPECTED IN SOILS. AQUEOUS HYDROLYSIS CAN CONTRIBUTE TO SOIL DEGRADATION, ESPECIALLY IN ALKALINE SOILS (3-DAY HALF LIFE AT PH 9). WILL BIODEGRADE IN AEROBIC WATERS WITH HALF-LIFE ON THE ORDER OF SE VERAL DAYS OR LESS. ==================== Disposal Considerations ==================== Waste Disposal Methods:AN ACCEPTABLE METHOD OF DISPOSAL IS TO BURN IN AN INCINERATOR IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REQUIREMENTS. APPROPRIATE REGULATORY AGENCIES SHOULD BE CONTACTED PRIOR TO DISPOSAL. =================== MSDS Transport Information =================== Transport Information:U.S. DEPT. OF TRANSPORTATION: SHIPPING NAME: NOT REGULATED IN NON-BULK SHIPMENT QUANTITIES. SEA (IMO/IMDG) SHIPPING NAME: ENVIRNMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S., (TRICRESYL PHOSPHATE, LESS T HAN 1% ORTHO-ISOMER). AIR (ICAO/IATA) SHIPPING NAME: NON-BULK SHIPMENTS NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE I I I SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR PART 355): NOT LISTED. SARA TITLE III, SECTION 311/312 HAZARDOUS CATEGORIZATION (40 CFR PART 370): DELAYED (CHRONIC) HEALTH HAZARD. SARA TITLE III SECTIONS 313 (40 CFR PART 372): NOT LISTED. Federal Regulatory Information:U.S. INVENTORY (TSCA): LISTED. CERCLA SECTIONS 102A/103 HAZARDOUS SUBSTANCES (40 CFR PART 302.4): NOT LISTED. USDA: STORE AND HANDLE AWAY FROM ANY PRODUCT INVOLVED IN FOOD PROCESSING. State Regulatory Information:NOT PROVIDED ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.