FISHER SCIENTIFIC, CHEMICAL DIV. -- 11189 HYDROGEN PEROXIDE 30-50% -- 6810-00-233-1711
===================== Product Identification ===================== Product ID:11189 HYDROGEN PEROXIDE 30-50% MSDS Date:04/29/1998 FSC:6810 NIIN:00-233-1711 Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 OR 201-796-7523 Emergency Phone Num:201-796-7100 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO Address:3970 JOHNS CREEK CT, SUITE 500 Box:City:SUWANEE State:GA ZIP:30024 Country:US Phone:770-871-4500 Contract Num:SP0450-00-M-D438 CAGE:8E930 Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN PEROXIDE (SARA 302) CAS:7722-84-1 RTECS #:MX0900000 Minumum % Wt:38. Code:F Maxumum % Wt:40. Code:F % Low Vol:29. Code:F % High Vol:32. Code:F Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:1 PPM; 9596 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:59.4 Code:F Maxumum % Wt:61.2 Code:F % Low Vol:68. Code:F % High Vol:71. Code:F Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL, RAT LD50:>90 ML/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: CONTACT WITH LIQUID IS CORROSIVE AND CAUSES SEVERE BURNS. SKIN: CAUSES SEVERE IRRITATION AND POSSIBLE BURNS. INHALATION: CAUSES CHEMICAL BURNS TO RESPIRATORY TRACT. MAY CAUSE ULCERATION OF NASAL TISSUE. INGESTION: MAY CAUSE SEVERE GASTROINTESTINAL TRACT IRRITATION AND POSSIBLE BURNS. MAY CAUSE STOMACH DISTENSION, POSSIBLE CELEBRAL SWELLING AND DEATH. CHRONIC: PROLONGED OR REPEATED C ONTACT MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:PER MSDS:HYDROGEN PEROXIDE: IARC:GROUP 3 CARCINOGEN. ACGIH: ANIMAL CARCINOGEN. Effects of Overexposure:EYES: CORRSION OF EYE TISSUE, BURNS. SKIN: SEVERE IRRITATION, BURNS, DERMATITIS. INHALATION: CHEMICAL BURNS OF RESPIRATORY TRACT, ULCERATION OF NASAL TISSUE, INSOMIA, NERVOUS TREMORS, NUMB EXTREMITIE S, CHEMICAL PNEUMONIA, UNCONSCIOUSNESS, DEATH. INGESTION: GI TRACT IRRITATION, NAUSEA, VOMITING, BURNS, VASCULAR COLLAPSE, AND DAMAGE, DIFFICULTY SWALLOWING, STOMACH DISTENSION, CEREBRAL SWELLING, D EATH. Medical Cond Aggravated by Exposure:TARGET ORGANS:CENTRAL NERVOUS SYSTEM, RESPIRATORY SYSTEM. ======================= First Aid Measures ======================= First Aid:EYES GET MEDICAL ATTENTION IMMEDIATELY. DO NOT ALLOW VICTIM TO RUB OR KEEP EYES CLOSED. EXTENSIVE IRRIGATON IS REQUIRED (AT LEAST 30 MINUTES). SKIN: GET MEDICAL ATTENTION IMMEDIATELY. FLUSH SKIN WITH PLENTY OF SOAP AND WATER FOR ATLEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. INHALATION: MOVE TO FRESH AIR. IF BREATHINGSING IS DIFFICULT, GIVE OXYGEN. DO NOT USE MOUTH TO MOUTH RESPIRATION. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. DO NOT INDUCE VOMITING. ALLOW VICTIM TO RINSE MOUTH AND THEN DRINK 2-4 CUP S OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Autoignition Temp:Autoignition Temp Text:NONCOM Lower Limits:40 Upper Limits:100 Extinguishing Media:USE WATER ONLY. DO NOT USE CARBON DIOXIDE, DO NOT USE DRY CHEMICAL. CONTACT PROFESSIONAL FIRE-FIGHTERS IMMEDIATELY. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN PRESSURE-DEMAND, MSHA/NIOSH (APPROVED OR EQUIVALENT), FULL PROTECTION GEAR. STRONG OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIALS MAY CAUSE FIRE. USE WATER SPR AY TO KEEP FIRE-EXPOSED CONTAINERS COOL. SUBSTANCE IS NONCOMBUSTIBLE. USE WATER WITH CAUTION AND IN FLOODING AMOUNTS. Unusual Fire/Explosion Hazard:STRONG OXIDIZER.CONTACT WITH COMBUSTIBLE MATERIALS MAY CAUSE FIRE. SUBSTANCE NON-COMBUSTIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PPERSONAL PROTECTION EQUIPMENT AS NEEDED. ABSORB SPILL WITH INERT MATERIAL (DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. CLEAN UP SPILLS IMMEDIATELY. USE WATER SPRAY TO D ISPERSE THE GAS/VAPOR. REMOVE ALL SOURCES OF IGNITION. SWEEP UP SOLID OR ABSORB LIQUID WITH INERT MATERIAL, THEN PLACE INTO A BIOHAZARD CONTAINER. WEAR PROTECTIVE EQUIPMENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. AVOID CONTACT WITH CLOTHING AND OTHER COMBUSTIBLE MATERIALS. DO NOT INGEST OR INHALE. STORE AWAY FROM HEAT, SPARKS, AND FLAM E. DO NOT STORE NEAR COMBUSTIBLE MATERIALS. DO NOT STORE IN DIRECT SUNLIGHT. Other Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE NIOSH-APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Protective Gloves:APPROPRIATE PROTECTIVE GLOVES. Eye Protection:PROTECTIVE EYEGLASS OR CHEMICAL SAFETY GOGGLES. Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATE CLOTHING AND LAUNDER BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:D3 Boiling Pt:=107.2C, 225.F Melt/Freeze Pt:=-32.2C, -26.F Decomp Temp:Decomp Text:N/AVAIL Vapor Pres:23 @30C Vapor Density:1.0 Spec Gravity:1.1-1.2 pH:2.5-3.5 Viscosity:1.25CP Evaporation Rate & Reference:>1.0 (N-BUTYL ACETATE=1) Solubility in Water:MISCIBLE IN WATER. Appearance and Odor:CLEAR, COLORLESS, LIQUID, ODOR: NONE. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE MATERIALS, COMBUSTIBLE MATERIAL, METALS, REDUCING AGENTS, ALKALINE MATERIALS, STRONG OXIDANTS. Stability Condition to Avoid:DECOMPOSES SLOWLY TO RELEASE OXYGEN. AVOID LIGHT, IGNITION SOURCES, DUST GENERATION, EXCESS HEAT. Hazardous Decomposition Products:OXYGEN, HYDROGEN GAS. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information =================== Toxicological Information:LD50/LC50: INHALATION RAT: CAS#7722-84-1: LC50=2 GM/M3, 4 HOURS; ORAL, MOUSE LD50= 2 GMS/KG; SKIN, RAT: LD50= 4060 MG/KG. CAS# 7732-18-5: ORAL, RAT: LD50= >90 ML/KG. CARCINOGENICITY: HYDROGEN PEROXIDE ; ACGIH: A3- ANIMAL CARCINOGEN. IARC: GROUP 3 CARCINOGEN. WATER: NOT LISTED BY ACGIH, IARC,NIOSH, NTP, OR OSHA. ===================== Ecological Information ===================== Ecological:NONE AVAILABLE. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA. =================== MSDS Transport Information =================== Transport Information:BASED ON MANUFACTURERS MSDS. US DOT: SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS 30%, HAZARD CLASS: 5.1, UN2014, PKG II. CANADIAN TDG: SHIPPING NAME: HYDROGEN PEROXIDE, HAZARD CLASS: 5.1 (8), UN2014. HOWEVER THE DOT SHIPPING NAME BASED ON 49 CFR PART 172.101 IS HYDROGEN PEROXIDE, AQUEOUS SOLUTIONS [WITH NOT LESS THAN 20% BUT NO MORE THAN 40% HYDROGEN PEROXIDE (STABILIZED AS NECESSARY)]. HA ZARD CLASS 5.1, 8, UN2014, PG II. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): CAS#7722-84-1; CONCENTRATIONS > 52%: TPQ= 1000 POUNDS; RQ= 1000 POUNDS. SARA CODES: CAS#7722-84-1: ACUTE, FLAMM ABLE. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION 313. Federal Regulatory Information:CLEAN AIR ACT: THIS MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS, CLASS 1 OZONE DEPLETORS, OR CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS H AZARDOUS SUBSTANCES UNDER THE CWA, NOR LISTED AS PRIORITY POLLUTANTS UNDER THE CWA, NOR LISTED AS TOXIC POLLUTANTS UNDER THE CWA. OSHA: CAS#7722-84-1 IS CONSIDERED HIGHLY HAZARDOUS BY OSHA. State Regulatory Information:HYDROGE PEROXIDE CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. WATERIS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, M A, FL, OR NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.