MALLINCKRODT BAKER INC -- 3032,ISOPROPYL ALCOHOL (90-100%) -- 6810-00-241-4709
===================== Product Identification ===================== Product ID:3032,ISOPROPYL ALCOHOL (90-100%) MSDS Date:09/08/1997 FSC:6810 NIIN:00-241-4709 Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151 Resp. Party Other MSDS Num.:I8840 Preparer's Name:NOT PROVIDED Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL CAS:67-63-0 RTECS #:NT8050000 Minumum % Wt:90. Maxumum % Wt:100. Other REC Limits:NOT PROVIDED OSHA PEL:980 MG/M3;400 PPM ACGIH TLV:983 MG/M3;400 PPM ACGIH STEL:1230 MG/M3;500 PPM Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:0. Maxumum % Wt:10. Other REC Limits:NOT PROVIDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) 5045 MG/KG Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: VAPORS IRRITATE RESPIRATORY TRACT. EXPOSURE TO HIGH CONCENTRATIONS HAS A NARCOTIC EFFECT, PRODUCING SYMPTOMS OF DIZZINESS, DROWSINESS, HEADACHE, UNCONSCIOUSNESS AND POSSIBLY DEATH. INGESTI ON: CAN CAUSE DROWSINESS, UNCONSCIOUSNESS, AND DEATH. GASTROINTESTINAL PAIN, CRAMPS, NAUSEA, VOMITING, AND DIARRHEA MAY ALSO RESULT. LETHAL DOSE FOR A HUMAN ADULT=ABOUT 8 OUNCES. SKIN: MAY CAUSE IRRI TATION WITH REDNESS AND PAIN. MAY BE ABSORBED THROUGH SKIN WITH POSSIBLE SYSTEMIC EFFECTS. EYE: VAPORS CAUSE IRRITATION. SPLASHES CAUSE SEVERE IRRITATION, POSSIBLE CORNEAL BURNS, EYE DAMAGE. CHRONIC E XPOSURE: MAY CAUSE SKIN EFFECTS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: VAPORS IRRITATE RESPIRATORY TRACT. EXPOSURE TO HIGH CONCENTRATIONS HAS A NARCOTIC EFFECT, PRODUCING SYMPTOMS OF DIZZINESS, DROWSINESS, HEADACHE, UNCONSCIOUSNESS AND POSSIBLY DEATH. INGESTI ON: CAN CAUSE DROWSINESS, UNCONSCIOUSNESS, AND DEATH. GASTROINTESTINAL PAIN, CRAMPS, NAUSEA, VOMITING, AND DIARRHEA MAY ALSO RESULT. SKIN: MAY CAUSE IRRITATION WITH REDNESS AND PAIN. EYE: VAPORS CAUS E IRRITATION. SPLASHES CAUSE SEVERE IRRITATION, POSSIBLE CORNEAL BURNS. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR IMPAIRED LIVER, KIDNEY OR PULMONARY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS AGENT. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. INGESTION: GIVE LARGE AMOUNT OF WATER TO DRINK. NEVER GIVE ANY THING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN IF IRRITATION DEVELOPS. EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=12.2C, 54.F Autoignition Temp:=398.9C, 750.F Lower Limits:2.0 Upper Limits:12.7 Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, CARBON DIOXIDE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL, DILUTE SPILLS TO NONFLAMMABLE MIXTURES, AND DISPERSE VAPORS. Fire Fighting Procedures:IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. WATER MAY B E USED TO PROTECT PERSONNEL ATTEMPTING TO STOP LEAK. Unusual Fire/Explosion Hazard:ABOVE FLASH POINT,VAPOR-AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. SENSITIVE TO STATIC DISCHARGE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. REMOVE ALL SOURCES OF IGNITION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. ISOLATE HAZARD AREA. KEEP UNPROTECTED PERSONNEL AWAY. CONTAIN AND RECOVER LIQUID WHEN POSSIBLE. USE NON-SPARKING TOOLS. COLLECT LIQUID IN AN APPROPRIATE CONTAINER/ABSORB WITH AN INERT MATERIAL (VERMICULITE, DRY SAND, EARTH). PLACE IN A CHEMICAL WASTE CONTAINER. DO NOT FLUSH TO SEWER. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE. STORE IN A COOL, DRY, WELL-VENTILATED LOCATION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE ACUTE. OUTSIDE OR DETACHED STORAGE IS PREFERRED. SEPARATE FROM INCOMPAT IBLES. CONTAINERS SHOULD BE BONDED AND GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS. Other Precautions:STORAGE AND USE AREAS SHOULD BE NO SMOKING AREAS. USE NON-SPARKING TOOLS AND EQUIPMENT, INCLUDING EXPLOSION PROOF VENTILATION. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED, A FULL FACEPIECE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE MAY BE WORN UP TO 50 TIMES THE EXPOSURE LIMIT OR THE MAXIMUM USE CONCENTRATION SPECIFIED BY APPROPRIATE REGULATORY AGENCY O R RESPIRATOR SUPPLIER, WHICHEVER IS LOWEST. WARNING: AIR-PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. Ventilation:A SYSTEM OF LOCAL OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURE BELOW THE AIRBORNE EXPOSURE LIMITS. LOCAL EXHAUST IS GENERALLY PREFERRED. Protective Gloves:NEOPRENE AND NITRILE RUBBER ARE RECOMMENDED MATERIALS. Eye Protection:USE CHEMICAL SAFETY GOGGLES AND/OR FULL FACE SHIELD WHERE SPLASHING IS POSSIBLE Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN CONTACT. Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health FOR EMERGENCIES OR INSTANCES WHERE THE EXPOSURE LEVELS ARE NOT KNOWN, USE A FULL-FACEPIECE POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR. ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=82.2C, 180.F Melt/Freeze Pt:=-89.C, -128.2F Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:44 @ 25C/77F Vapor Density:2.1 Spec Gravity:0.79 pH:NO INFORMATION Viscosity:NOT PROVIDED Evaporation Rate & Reference:2.83 (BUTYL ACETATE=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID - RUBBING ALCOHOL ODOR Percent Volatiles by Volume:100 Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HEAT, FLAME, STRONG OXIDIZERS, ACETALDEHYDE, ACIDS, CHLORINE, ETHYLENE OXIDE, HYDROGEN-PALLADIUM COMBINATION, HYDROGEN PEROXIDE-SULFURIC ACID, POTASSIUM TERT-BUTOXIDE, HYPOCHLOROUS ACID, ISOCYANATES, NITROFORM, PHOSGENE, OL Stability Condition to Avoid:HEAT, FLAME, IGNITION SOURCES AND INCOMPATIBLES. SUNLIGHT Hazardous Decomposition Products:NOT PROVIDED =================== Toxicological Information =================== Toxicological Information:INHALATION RAT LC50: 16,000 PPM/8H; SKIN RABBIT LD50: 12.8 G/KG. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: WHEN RELEASED INTO THE SOIL, THIS MATERIAL IS EXPECTED TO QUICKLY EVAPORATE , LEACH INTO GROUNDWATER, BIODEGRADE TO A MODERATE EXTENT. WHEN RELEASED TO WATER, THIS MATERIAL IS EXPE CTED TO QUICKLY EVAPORATE, HALF-LIFE OF 1 AND 10 DAYS, BIODEGRADE TO A MODERATE EXTENT. NOT EXPECTED TO SIGNIFICANTLY BIOACCUMULATE. WHEN RELEASED INTO THE AIR, THIS MATERIAL IS EXPECTED TO READILY DE GRADED BY REACTION WITH PHOTOCHEMICALLY PRODUCED HYDROXYL RADICALS AND HAVE A HALF-LIFE BETWEEN 1 AND 10 DAYS. ENVIRONMENTAL TOXICITY: THE LC50/96 HOUR VALUES FOR FISH ARE OVER 100 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE AND SENT TO A RCRA APPROVED INCINERATOR OR DISPOSED IN A RCRA APPROVED WASTE FACILITY. PROCESSING, USE OR CONTAM INATION OF THIS PRODUCT MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE AND LOCAL DISPOSAL REGUALTIONS MA Y DIFFER FROM FEDERAL. =================== MSDS Transport Information =================== Transport Information:DOMESTIC (LAND, D.O.T.): PROPER SHIPPING NAME: ISOPROPANOL. HAZARD CLASS: 3. UN/NA: UN1219. PACKING GROUP: II. INFORMATION REPORTED FOR PRODUCT/SIZE: 355 LB. INTERNATIONAL (WATER, I.M.O.): PROPER SHIP PING NAME: ISOPROPANOL. HAZARD CLASS: 3.2. UN/NA: UN1219. PACKING GROUP: II. INFORMATION REPORTED FOR PRODUCT/SIZE: 355 LB ===================== Regulatory Information ===================== SARA Title III Information:SARA 311/312: ACUTE: YES CHRONIC: YES FIRE: YES. Federal Regulatory Information:TSCA: YES. State Regulatory Information:NOT PROVIDED ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.