MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Elmer's Products, Inc. |
Emergency Phone Number: |
1 Easton Oval |
Poison Control Center |
Columbus, OH 43219 |
1-888-516-2502 |
For
additional product information, access our website at www.elmers.com or call
1-888-435-6377. To place an order, call 1-800-848-9400.
SUBSTANCE: ELMER'S NO-WRINKLE RUBBER
CEMENT
TRADE NAMES/SYNONYMS:
E904; E231; E232; E233;
E61518
PRODUCT USE: adhesives
CREATION DATE: May 02
2003
REVISION DATE: Nov 07 2005
2. COMPOSITION, INFORMATION ON INGREDIENTS
COMPONENT: HEPTANE
CAS NUMBER: 142-82-5
PERCENTAGE:
>70
COMPONENT: ISOPROPYL ALCOHOL
CAS NUMBER:
67-63-0
PERCENTAGE: 1-5
3. HAZARDS IDENTIFICATION
NFPA
RATINGS (SCALE
0-4): HEALTH=2 FIRE=3 REACTIVITY=0
EMERGENCY
OVERVIEW:
PHYSICAL FORM: liquid
ODOR: mild odor, solvent
odor
MAJOR HEALTH HAZARDS: potentially fatal if swallowed, respiratory
tract irritation, skin irritation, eye irritation, central nervous system
depression, allergic reactions
PHYSICAL HAZARDS: Flammable liquid
and vapor. Vapor may cause flash fire.
POTENTIAL HEALTH
EFFECTS:
INHALATION:
SHORT TERM EXPOSURE: irritation,
changes in blood pressure, nausea, vomiting, stomach pain, chest pain,
difficulty breathing, irregular heartbeat, headache, drowsiness, dizziness,
disorientation, emotional disturbances, hallucinations, loss of coordination,
suffocation, internal bleeding, kidney damage, unconsciousness, coma
LONG
TERM EXPOSURE: no information on significant adverse effects
SKIN
CONTACT:
SHORT TERM EXPOSURE: irritation, allergic reactions,
absorption may occur, changes in blood pressure, nausea, vomiting, irregular
heartbeat, headache, drowsiness, dizziness, loss of coordination
LONG TERM
EXPOSURE: irritation
EYE CONTACT:
SHORT TERM EXPOSURE:
irritation, eye damage
LONG TERM EXPOSURE:
irritation
INGESTION:
SHORT TERM EXPOSURE: potentially fatal
if swallowed, irritation, changes in blood pressure, nausea, vomiting, diarrhea,
stomach pain, difficulty breathing, irregular heartbeat, headache, drowsiness,
dizziness, disorientation, emotional disturbances, hallucinations, loss of
coordination, internal bleeding, kidney damage, unconsciousness, coma
LONG
TERM EXPOSURE: no information on significant adverse effects
4. FIRST AID MEASURES
INHALATION: If adverse effects occur, remove to uncontaminated area. Give
artificial respiration if not breathing. Get immediate medical
attention.
SKIN CONTACT: If bonding occurs, immerse the bonded
surfaces in warm soapy water. Peel or roll the surfaces apart using a blunt
edge, such as a spatula or spoon handle. Do not pull surfaces apart with a
direct opposing action. If burns occur, treat as thermal burns. Get medical
attention, if needed.
EYE CONTACT: If bonding to tissues occurs,
wash with large amounts of warm water. Cover both eyes with sterile, dry
bandages. The eye will open without further action. Do not pull surfaces apart
with a direct opposing action. If burns occur, treat as thermal burns. Get
medical attention.
INGESTION: Wet lips with water. Peel or roll
the surfaces apart using a blunt edge, such as a spatula or spoon handle. Do not
pull surfaces apart with a direct opposing action. If a lump forms in the mouth,
turn head to side. If burns occur, treat as thermal burns. Get medical
attention.
NOTE TO PHYSICIAN: Mineral oil, vegetable oil, or
petroleum jelly may help soften the bonding between skin surfaces. For skin
contact, consider acetone or nitromethane.
5. FIRE FIGHTING MEASURES
FIRE AND EXPLOSION HAZARDS: Severe fire hazard. The vapor is heavier than
air. Vapors or gases may ignite at distant ignition sources and flash back.
Vapor/air mixtures are explosive.
EXTINGUISHING MEDIA: carbon
dioxide, regular dry chemical, regular foam, water
FIRE FIGHTING:
Move container from fire area if it can be done without risk. Cool containers
with water spray until well after the fire is out. Flood with fine water spray.
Do not scatter spilled material with high-pressure water streams. Avoid
inhalation of material or combustion by-products. Stay upwind and keep out of
low areas.
FLASH POINT: 25 F (-4 C) (TCC)
FLAMMABILITY CLASS
(OSHA): IB
6. ACCIDENTAL RELEASE MEASURES
OCCUPATIONAL RELEASE:
Avoid heat, flames, sparks and other sources of
ignition. Stop leak if possible without personal risk. Reduce vapors with water
spray. Small spills: Absorb with sand or other non-combustible material. Collect
spilled material in appropriate container for disposal.
7. HANDLING AND STORAGE
STORAGE: Store and handle in accordance with all current regulations and
standards. Store in a cool, dry place. Store in a tightly closed container.
Store in a well-ventilated area. Avoid heat, flames, sparks and other sources of
ignition. Subject to storage regulations: U.S. OSHA 29 CFR 1910.106. Grounding
and bonding required. See original container for storage recommendations. Keep
separated from incompatible substances.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE LIMITS:
HEPTANE:
500 ppm (2000 mg/m3) OSHA
TWA
400 ppm (1640 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30,
1993)
500 ppm (2050 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30,
1993)
400 ppm ACGIH TWA
500 ppm ACGIH STEL
85 ppm (350 mg/m3) NIOSH
recommended TWA 10 hour(s)
440 ppm (1800 mg/m3) NIOSH recommended ceiling 15
minute(s)
ISOPROPYL ALCOHOL:
ISOPROPYL ALCOHOL (ISOPROPANOL;
2-PROPANOL):
400 ppm (980 mg/m3) OSHA TWA
500 ppm (1230 mg/m3) OSHA
STEL (vacated by 58 FR 35338, June 30, 1993)
200 ppm ACGIH TWA
400 ppm
ACGIH STEL
400 ppm (980 mg/m3) NIOSH recommended TWA 10 hour(s)
500 ppm
(1225 mg/m3) NIOSH recommended STEL
VENTILATION: Ventilation
equipment should be explosion-resistant if explosive concentrations of material
are present. Provide local exhaust or process enclosure ventilation system.
Ensure compliance with applicable exposure limits.
EYE PROTECTION:
Wear splash resistant safety goggles with a faceshield. Provide an emergency eye
wash fountain and quick drench shower in the immediate work
area.
CLOTHING: Wear appropriate chemical resistant
clothing.
GLOVES: Wear appropriate chemical resistant
gloves.
RESPIRATOR: Under conditions of frequent use or heavy
exposure, respiratory protection may be needed. Respiratory protection is ranked
in order from minimum to maximum. Consider warning properties before use.
Any
chemical cartridge respirator with organic vapor cartridge(s).
Any chemical
cartridge respirator with a full facepiece and organic vapor
cartridge(s).
Any air-purifying respirator with a full facepiece and an
organic vapor canister.
For Unknown Concentrations or Immediately
Dangerous to Life or Health -
Any supplied-air respirator with full
facepiece and operated in a pressure-demand or other positive-pressure mode in
combination with a separate escape supply.
Any self-contained breathing
apparatus with a full facepiece.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: liquid
APPEARANCE: opaque
ODOR: mild
odor, solvent odor
BOILING POINT: 194 F (90 C)
FREEZING
POINT: Not available
VAPOR PRESSURE: Not available
VAPOR
DENSITY (air=1): >1
SPECIFIC GRAVITY (water=1):
0.71
WATER SOLUBILITY: almost insoluble
PH: Not
available
VOLATILITY: 90%
ODOR THRESHOLD: Not
available
EVAPORATION RATE: <1 (ether=1)
COEFFICIENT OF
WATER/OIL DISTRIBUTION: Not available
10. STABILITY AND REACTIVITY
REACTIVITY: Stable at normal temperatures and
pressure.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and
other sources of ignition. Containers may rupture or explode if exposed to heat.
Keep out of water supplies and sewers.
INCOMPATIBILITIES: acids,
bases, amines, oxidizing materials
HAZARDOUS
DECOMPOSITION:
Thermal decomposition products: oxides of
carbon
POLYMERIZATION: Will not polymerize.
11. TOXICOLOGICAL INFORMATION
HEPTANE:
TOXICITY DATA:
103 gm/m3/4 hour(s) inhalation-rat
LC50
LOCAL EFFECTS:
Irritant: inhalation, skin, eye
ACUTE
TOXICITY LEVEL:
Slightly Toxic: inhalation
TARGET ORGANS:
central nervous system
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
respiratory disorders, skin disorders and allergies
ADDITIONAL DATA:
Stimulants such as epinephrine may induce ventricular
fibrillation.
ISOPROPYL ALCOHOL:
IRRITATION DATA:
500
mg skin-rabbit mild; 100 mg eyes-rabbit severe; 10 mg eyes-rabbit moderate; 100
mg/24 hour(s) eyes-rabbit moderate
TOXICITY DATA:
16000 ppm/8
hour(s) inhalation-rat LC50; 12800 mg/kg skin-rabbit LD50; 5000 mg/kg oral-rat
LD50
CARCINOGEN STATUS: IARC: Human Inadequate Evidence, Animal
Inadequate Evidence, Group 3; ACGIH: A4 -Not Classifiable as a Human
Carcinogen
LOCAL EFFECTS:
Irritant: inhalation, eye
ACUTE
TOXICITY LEVEL:
Moderately Toxic: inhalation, ingestion
Slightly
Toxic: dermal absorption
TARGET ORGANS: central nervous
system
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: kidney disorders,
liver disorders, respiratory disorders, skin disorders and
allergies
MUTAGENIC DATA: Available.
REPRODUCTIVE EFFECTS
DATA: Available.
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Dispose in accordance with all applicable regulations. Subject to disposal
regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001.
14. TRANSPORT INFORMATION
U.S. DOT 49 CFR 172.101:
PROPER SHIPPING NAME: Consumer
commodity
HAZARD CLASS OR DIVISION: ORM-D
LABELING
REQUIREMENTS: None
CANADIAN TRANSPORTATION OF DANGEROUS GOODS:
No classification assigned.
15. REGULATORY INFORMATION
U.S. REGULATIONS:
CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Not regulated.
SARA TITLE III SECTION
302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not
regulated.
SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES
(40 CFR 355.40): Not regulated.
SARA TITLE III SARA SECTIONS
311/312 HAZARDOUS CATEGORIES (40 CFR 370.21):
ACUTE: Yes
CHRONIC:
No
FIRE: Yes
REACTIVE: No
SUDDEN RELEASE: No
SARA TITLE III
SECTION 313 (40 CFR 372.65):
ISOPROPYL ALCOHOL, STRONG ACID PROCESS
ONLY
OSHA PROCESS SAFETY (29CFR1910.119): Not
regulated.
STATE REGULATIONS:
California Proposition
65: Not regulated.
CANADIAN
REGULATIONS:
CONTROLLED PRODUCTS REGULATIONS (CPR): This
product has been classified in accordance with the criteria of the Controlled
Products Regulations (CPR) and the MSDS contains all of the information required
by the CPR.
WHMIS CLASSIFICATION: D2B, B2.
NATIONAL
INVENTORY STATUS:
U.S. INVENTORY (TSCA): All the components of
this substance are listed on or are exempt from the inventory.
TSCA
12(b) EXPORT NOTIFICATION:
HEPTANE
CAS NUMBER:
142-82-5
SECTION 4
CANADA INVENTORY (DSL/NDSL): All components
of this product are listed on the DSL.
16. OTHER INFORMATION
©Copyright 1984-2005 MDL Information Systems, Inc. All
rights reserved.
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR
THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind shall
be greater in amount than the purchase price of the quantity of product in
respect of which damages are claimed. In no event shall Seller be liable for
incidental or consequential damages, whether Buyer's claim is based on contract,
breach of warranty, negligence or otherwise.